CHEMISTRY: Designing Carbenes
نویسندگان
چکیده
منابع مشابه
The surface chemistry of methylene iodide adsorbed on clean and oxygen-covered Mo(100): formation and chemistry of carbenes
Carbene species are grafted onto Mo(100) by the thermal decomposition of methylene iodide, where the decomposition is followed using ultraviolet photoelectron spectroscopy. Carbenes hydrogenate to methane by reaction with surface hydrogen via a secondorder reaction with an activation energy of 21 ___ 2 kJ mol1. Experiments with deuterium show that there appears to be no hydrogendeuterium exchan...
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ژورنال
عنوان ژورنال: Science
سال: 2005
ISSN: 0036-8075,1095-9203
DOI: 10.1126/science.309.5738.1155b